Πέμπτη 27 Ιουνίου 2019

Unconventional CN vacancies suppress iron-leaching in Prussian blue analogue pre-catalyst for boosted oxygen evolution catalysis
Nature Communications, Published online: 26 June 2019; doi:10.1038/s41467-019-10698-9Defect-engineering offers a promising route to vary material properties and reactivities, although the achievable defect types are limited. Here, the authors introduced unusual CN-vacancies in Prussian blue analogue pre-catalysts that can limit Fe leaching and improve oxygen evolution performances.
Nature Communications - current - nature.com science feeds
Wed Jun 26, 2019 03:00
From choice architecture to choice engineering
Nature Communications, Published online: 26 June 2019; doi:10.1038/s41467-019-10825-6Qualitative psychological principles are commonly utilized to influence the choices that people make. Can this goal be achieved more efficiently by using quantitative models of choice? Here, we launch an academic competition to compare the effectiveness of these two approaches.
Nature Communications - current - nature.com science feeds
Wed Jun 26, 2019 03:00
Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts
Nature Communications, Published online: 26 June 2019; doi:10.1038/s41467-019-09832-4Catalytic transformations involving main group compounds is much less developed than carbon chemistry. Here, the authors report the use of catalytic or stoichiometric tBuOK in presence of a hydrogen acceptor for efficient P–P and P–heteroatom coupling reactions.
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Wed Jun 26, 2019 03:00
Insights into real-time chemical processes in a calcium sensor protein-directed dynamic library
Nature Communications, Published online: 26 June 2019; doi:10.1038/s41467-019-10627-wDynamic combinatorial chemistry (DCC) is instrumental in the discovery of ligands for pharmaceutical targets. Here, the authors adapted DCC to work at 4 degrees Celsius and used it to identify a ligand for Neuronal Calcium Sensor-1 that promotes NCS-1/Ric8a protein-protein interaction.
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Wed Jun 26, 2019 03:00
DOT1L inhibition reveals a distinct subset of enhancers dependent on H3K79 methylation
Nature Communications, Published online: 26 June 2019; doi:10.1038/s41467-019-10844-3Histone 3 lysine 79 is mono (me1), di (me2), or tri (me3) methylated by the methyltransferase DOT1L. Here the authors reveal a group of enhancers defined by H3K79me2/3 which regulates enhancer-promoter interactions and other key enhancer features in MLL-AF4 leukemia cells.
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Wed Jun 26, 2019 03:00
TGFβ-induced degradation of TRAF3 in mesenchymal progenitor cells causes age-related osteoporosis
Nature Communications, Published online: 26 June 2019; doi:10.1038/s41467-019-10677-0Increased inflammation during ageing promotes osteoporosis by activating osteoclast function and inhibiting osteoblasts. Here, the authors show that TGFβ1 release from bone matrix during ageing induces degradation of TRAF3 in mesenchymal progenitor cells, leading to reduced osteoblast differentiation and increased osteoclast formation, and suggesting that pharmacological stabilization of TRAF3 could ameliorate age-related...
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Wed Jun 26, 2019 03:00
Interlayer epitaxy of wafer-scale high-quality uniform AB-stacked bilayer graphene films on liquid Pt<sub>3</sub>Si/solid Pt
Nature Communications, Published online: 26 June 2019; doi:10.1038/s41467-019-10691-2Specific stacking sequence of graphene can enable observation of unusual properties however it has been difficult to obtain this over wider areas. Here, the authors report wafer-scale growth of 100% AB-stacked bilayer graphene films by CVD on liquid Pt3Si/solid Pt substrates showing high quality and improved mechanical properties comparable to the mechanically exfoliated flakes.
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Wed Jun 26, 2019 03:00

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